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. 2005 Nov 30;127(47):16362-3.
doi: 10.1021/ja055528o.

A metal-organic framework functionalized with free carboxylic acid sites and its selective binding of a Cl(H2O)4(-) cluster

Radu Custelcean  1 , Maryna G Gorbunova
Affiliations

A metal-organic framework functionalized with free carboxylic acid sites and its selective binding of a Cl(H2O)4(-) cluster

Radu Custelcean et al. J Am Chem Soc. .

Abstract

A metal-organic framework with one-dimensional channels decorated with -COOH binding sites was synthesized under aqueous acidic conditions, which inhibited the participation of these groups to metal coordination or self-association by hydrogen bonding. This material selectively includes Cl(H2O)4- clusters in its channels, as revealed by single-crystal X-ray diffraction analysis, which represents the first structural characterization of such a water-chloride cluster.

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