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. 2006 Jan 21:(3):314-6.
doi: 10.1039/b513712h. Epub 2005 Nov 21.

Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer

Emma Denehy  1 , Jonathan M White, Spencer J Williams
Affiliations

Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer

Emma Denehy et al. Chem Commun (Camb). .

Abstract

Structure/reactivity and structure/structure correlations of 5 sulfate monoesters and 11 sulfamate esters determined by low temperature X-ray crystallography reveal similar ground state deformations that suggest similar reaction coordinates for sulfuryl and sulfamyl group transfer.

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