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. 2006 Jan 18;128(2):408-9.
doi: 10.1021/ja057434k.

Titanium(II)-mediated cyclizations of (silyloxy)enynes: a total synthesis of (-)-7-demethylpiericidin A1

Katie A Keaton  1 , Andrew J Phillips
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Titanium(II)-mediated cyclizations of (silyloxy)enynes: a total synthesis of (-)-7-demethylpiericidin A1

Katie A Keaton et al. J Am Chem Soc. .

Abstract

A concise total synthesis of 7-demethylpiericidin A1 has been completed. The synthesis features a titanium(II)-mediated cyclization of a (silyloxy)enyne as the key step and proceeds in nine steps from tiglic aldehyde.

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