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. 2006 Feb 8;128(5):1424-5.
doi: 10.1021/ja054109o.

Highly enantioselective synthesis of tetrahydro-beta-carbolines and tetrahydro-gamma-carbolines via Pd-catalyzed intramolecular allylic alkylation

Marco Bandini  1 , Alfonso Melloni, Fabio Piccinelli, Riccardo Sinisi, Simona Tommasi, Achille Umani-Ronchi
Affiliations

Highly enantioselective synthesis of tetrahydro-beta-carbolines and tetrahydro-gamma-carbolines via Pd-catalyzed intramolecular allylic alkylation

Marco Bandini et al. J Am Chem Soc. .

Abstract

A novel Pd-catalyzed intramolecular allylic alkylation of indoles allows THBCs and THGCs to be effectively synthesized in high yields and excellent enantiomeric excesses (ee up to 97%).

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