Palladium(II)-catalyzed aerobic dialkoxylation of styrenes: a profound influence of an o-phenol
- PMID: 16448111
- DOI: 10.1021/ja0579053
Palladium(II)-catalyzed aerobic dialkoxylation of styrenes: a profound influence of an o-phenol
Abstract
We report a Pd(II)-catalyzed aerobic dialkoxylation of styrene derivatives that requires an o-phenol. Initial scope and preliminary mechanistic studies are presented in which the o-phenol is proposed to facilitate the formation of a quinone methide intermediate.
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