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. 1975 May;14(3):227-32.
doi: 10.1016/0009-3084(75)90003-1.

13-C NMR investigation of phospholipid membranes with the aid of shift reagents

13-C NMR investigation of phospholipid membranes with the aid of shift reagents

Y E Shapiro et al. Chem Phys Lipids. 1975 May.

Abstract

13-C NMR spectra of sonicated phospholipid dispersions have been investigated with the aid of paramagnetic ions (Pr-3+) as shift reagents. This method permits discrimination between the outer and the inner surfaces of the vesicular membrane and gives a larger variety of signals than 1-H NMR. The lanthanide induced shifts have been found to depend on other ions present and on the lipid composition of the membrane.

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