A suggestion for naming faces of ring compounds
- PMID: 16592816
- PMCID: PMC349414
- DOI: 10.1073/pnas.77.5.2439
A suggestion for naming faces of ring compounds
Abstract
Discussion of the topology of interaction of ring compounds with macromolecules and receptors requires a system for naming the faces of the cyclic compound. An alpha/beta-face nomenclature is suggested that is based on the clockwise/counterclockwise direction of ascending numbering in the ring with the lowest numbered unshared ring atom. This system is applicable to a very broad range of compounds: sugars, cyclic bases, steroids, cyclitols, porphyrins, etc., and molecules with a single ring, fused rings, encompassing rings, and rings formed by head-to-tail polymerization.
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