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. 2006 Apr 13;8(8):1673-6.
doi: 10.1021/ol0602809.

Temporary phosphate tethers: a metathesis strategy to differentiated polyol subunits

Joshua D Waetzig  1 , Paul R Hanson
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Temporary phosphate tethers: a metathesis strategy to differentiated polyol subunits

Joshua D Waetzig et al. Org Lett. .

Abstract

[reaction: see text] Studies probing reactivity and selectivity of cross metathesis (CM) with an exocyclic olefin in a P-chiral bicyclo[4.3.1]phosphate triester are described. Studies have revealed a Type III CM reactivity pattern for the exocyclic olefin within this phosphate triester. This versatile method allows for simple, selective manipulation of a P-chiral building block en route to advanced polyol subunits.

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