Bisphosphine based hetero-capsules for the encapsulation of transition metals
- PMID: 16609776
- DOI: 10.1039/b518274c
Bisphosphine based hetero-capsules for the encapsulation of transition metals
Abstract
Just mixing of solutions of tetracationic diphosphine ligands and tetraanionic calix[4]arene building blocks leads to the formation of supramolecular heterocapsules that coordinate a palladium metal within the cavity of the assembly, giving rise to a new class of potential supramolecular transition metal catalysts.
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