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. 2006 Jun 14;128(23):7414-5.
doi: 10.1021/ja058095y.

Highly selective cobalt-catalyzed hydrovinylation of styrene

Michiel M P Grutters  1 , Christian Müller, Dieter Vogt
Affiliations

Highly selective cobalt-catalyzed hydrovinylation of styrene

Michiel M P Grutters et al. J Am Chem Soc. .

Abstract

The hydrovinylation reaction is a codimerization of a 1,3-diene or vinyl arene and ethene with great potential for fine chemicals and pharmaceuticals. For the first time, enantioselective cobalt-catalyzed hydrovinylations of styrene were achieved with a cobalt-based system bearing a chiral bis(phosphine)amide ligand.

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