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. 2006 May 14:(18):1980-2.
doi: 10.1039/b600597g. Epub 2006 Apr 3.

This facile interconversion of dinuclear double helicates and side-by-side species: a reprogrammable ligand with potential sensor applications

Georgios Bokolinis  1 , T Riis-Johannessen, Lindsay P Harding, John C Jeffery, Neil McLay, Craig R Rice
Affiliations

This facile interconversion of dinuclear double helicates and side-by-side species: a reprogrammable ligand with potential sensor applications

Georgios Bokolinis et al. Chem Commun (Camb). .

Abstract

The ligand L1 forms a dinuclear double helicate with Cu+ but upon addition of Ba2+ to the system a side-by-side species is formed both in solution and in the solid state; in the presence of Na+ both the helicate and the side-by-side species are formed in roughly equal amounts in solution.

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