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. 2005 Mar 17;109(10):4624-30.
doi: 10.1021/jp0461246.

Electrochemical behavior of poly(ferrocenyldimethylsilane-b-dimethylsiloxane) films

Tao Chen  1 , Li Wang, Guohua Jiang, Jianjun Wang, Xiaochen Dong, Xuejie Wang, Junfeng Zhou, Chiliang Wang, Wei Wang
Affiliations

Electrochemical behavior of poly(ferrocenyldimethylsilane-b-dimethylsiloxane) films

Tao Chen et al. J Phys Chem B. .

Abstract

The electrochemical behavior of poly(ferrocenyldimethylsilane-b-dimethylsiloxane) (PFDMS-b-PDMS) films deposited on a glassy carbon electrode was investigated by means of cyclic voltammetry (CV). The influences of the solvent, film thickness, temperature, and PDMS block length in PFDMS-b-PDMS on the electrode process were discussed. It was found that in 0.1 M aqueous LiClO(4) the electrochemical processes of the films on a glassy carbon electrode were complex and have a low rate of electron transport and mass diffusion. The kinetic parameters obtained indicated that the electrode process was controlled by both the electrode reaction and mass diffusion.

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