doi: 10.1021/jo060016t.
Nitrene transfer reactions catalyzed by gold complexes
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- PMID: 16872166
- DOI: 10.1021/jo060016t
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Nitrene transfer reactions catalyzed by gold complexes
J Org Chem.
.
Abstract
We report here the first gold-catalyzed nitrene transfer reaction. A gold(I) compound, supported by 4,4',4' '-tri-tert-butyl-2,2':6',2' '-terpyridine (tBu3tpy) as the ligand, efficiently catalyzes olefin aziridination with the use of the commercially available oxidant PhI(OAc)2 and sulfonamides. This system also mediates carbene insertion into benzene.
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