doi: 10.1039/b607916d.
Epub 2006 Jul 31.
Methyl and arylchalcogenolate complexes of cadmium in a sulfur rich coordination environment: syntheses and structural characterization of the tris(2-mercapto-1-tert-butylimidazolyl)hydroborato cadmium complexes [Tm(Bu(t))]CdMe, and [Tm(Bu(t))]CdEAr (E = O, S, Se, Te) and analysis of the bonding in chalcogenolate compounds
Affiliations
- PMID: 16932812
- DOI: 10.1039/b607916d
Item in Clipboard
Methyl and arylchalcogenolate complexes of cadmium in a sulfur rich coordination environment: syntheses and structural characterization of the tris(2-mercapto-1-tert-butylimidazolyl)hydroborato cadmium complexes [Tm(Bu(t))]CdMe, and [Tm(Bu(t))]CdEAr (E = O, S, Se, Te) and analysis of the bonding in chalcogenolate compounds
Dalton Trans.
.
Abstract
A series of arylchalcogenolate complexes of cadmium supported by tris(2-mercapto-1-tert-butylimidazolyl)hydroborato ligation, namely [Tm(Bu(t))]CdEAr (EAr = OC(6)H(3)Ph(2), SPh, SePh, TePh), has been synthesized from [Tm(Bu(t))]CdMe; structural characterization by X-ray diffraction indicates that the variation in Cd-EAr bond lengths is similar to that of Zn-EAr and correlates closely with the covalent radius of the chalcogen, in marked contrast to the large variation in M-OAr and M-SAr bond lengths observed for other metals (Zr and Sm).
Similar articles
-
Synthesis and structures of cadmium carboxylate and thiocarboxylate compounds with a sulfur-rich coordination environment: carboxylate exchange kinetics involving tris(2-mercapto-1-t-butylimidazolyl)hydroborato cadmium complexes, [Tm(Bu(t))]Cd(O2CR).Inorg Chem. 2015 Apr 20;54(8):3835-50. doi: 10.1021/acs.inorgchem.5b00017. Epub 2015 Mar 31. Inorg Chem. 2015. PMID: 25826184 Free PMC article.
-
Methyl, hydrochalcogenido, and phenylchalcogenolate complexes of zinc in a sulfur rich coordination environment: syntheses and structural characterization of the tris(2-mercapto-1-tert-butylimidazolyl)hydroboratozinc complexes [TmBut]ZnMe, [TmBut]ZnEH (E = S, Se) and [TmBut]ZnEPh (E = O, S, Se, Te).Chem Commun (Camb). 2004 Dec 21;(24):2870-1. doi: 10.1039/b412218f. Epub 2004 Oct 25. Chem Commun (Camb). 2004. PMID: 15599448
-
Monovalent indium in a sulfur-rich coordination environment: synthesis, structure and reactivity of tris(2-mercapto-1-tert-butylimidazolyl)hydroborato indium, [TmBut]In.Chem Commun (Camb). 2008 Jul 28;(28):3305-7. doi: 10.1039/b803037e. Epub 2008 Jun 2. Chem Commun (Camb). 2008. PMID: 18622452
-
Molecular structures of tris(2-mercapto-1-tert-butylimidazolyl)hydroborato and tris(2-mercapto-1-adamantylimidazolyl)hydroborato sodium complexes: analysis of [Tm(R)] ligand coordination modes and conformations.Dalton Trans. 2014 Jul 28;43(28):10852-65. doi: 10.1039/c4dt01271b. Dalton Trans. 2014. PMID: 24898480
-
Exchange of Alkyl and Tris(2-mercapto-1-t-butylimidazolyl)hydroborato Ligands Between Zinc, Cadmium and Mercury.J Organomet Chem. 2015 Sep 1;792:177-183. doi: 10.1016/j.jorganchem.2015.04.014. J Organomet Chem. 2015. PMID: 26273109 Free PMC article.
Cited by
-
Synthesis and structural characterization of tris(2-mercapto-1-methylbenzimidazolyl)hydroborato cadmium halide complexes, {[Tm(MeBenz)]Cd(μ-Cl)}2 and [Tm(MeBenz)]CdI: a rare example of cadmium in a trigonal bipyramidal sulfur-rich coordination environment.Dalton Trans. 2014 Oct 7;43(37):13874-82. doi: 10.1039/c4dt01820f. Epub 2014 Aug 8. Dalton Trans. 2014. PMID: 25105778 Free PMC article.
-
Synthesis, structure and reactivity of a terminal magnesium fluoride compound, [TpBut,Me]MgF: hydrogen bonding, halogen bonding and C-F bond formation.Chem Sci. 2016 Jan 1;7(1):142-149. doi: 10.1039/c5sc03504j. Epub 2015 Nov 17. Chem Sci. 2016. PMID: 29861975 Free PMC article.
-
Coordination of 1-methyl-1,3-dihydro-2H-benzimidazole-2-selone to zinc and cadmium: Monotonic and non-monotonic bond length variations for [H(sebenzimMe)]2MCl2 complexes (M = Zn, Cd, Hg).Polyhedron. 2019 May 15;164:185-194. doi: 10.1016/j.poly.2019.01.018. Epub 2019 Jan 14. Polyhedron. 2019. PMID: 31333278 Free PMC article.
-
Synthesis and structures of cadmium carboxylate and thiocarboxylate compounds with a sulfur-rich coordination environment: carboxylate exchange kinetics involving tris(2-mercapto-1-t-butylimidazolyl)hydroborato cadmium complexes, [Tm(Bu(t))]Cd(O2CR).Inorg Chem. 2015 Apr 20;54(8):3835-50. doi: 10.1021/acs.inorgchem.5b00017. Epub 2015 Mar 31. Inorg Chem. 2015. PMID: 25826184 Free PMC article.
-
On the chalcogenophilicity of mercury: evidence for a strong Hg-Se bond in [Tm(Bu(t))]HgSePh and its relevance to the toxicity of mercury.J Am Chem Soc. 2010 Jan 20;132(2):647-55. doi: 10.1021/ja907523x. J Am Chem Soc. 2010. PMID: 20020759 Free PMC article.
LinkOut - more resources
Full Text Sources
Miscellaneous
