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. 2006 Oct 14:(38):4531-8.
doi: 10.1039/b607964d. Epub 2006 Aug 8.

Structure and O2-reactivity of copper(I) complexes supported by pyridylalkylamine ligands

Shinobu Itoh  1 , Yoshimitsu Tachi
Affiliations

Structure and O2-reactivity of copper(I) complexes supported by pyridylalkylamine ligands

Shinobu Itoh et al. Dalton Trans. .

Abstract

The structure and O2-reactivity of a series of copper(I) complexes supported by the pyridylalkylamine ligands are summarized, and the ligand effects such as the chelate ring size effect (five- vs. six-membered ring), the denticity effect (tetradentate vs. tridentate vs. didentate), the steric effect of 6-methylpyridine and the steric and/or electronic effects of N-alkyl substituents are discussed in detail.

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