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. 2007 Jan 1;17(1):183-8.
doi: 10.1016/j.bmcl.2006.09.066. Epub 2006 Oct 10.

Phosphate transfer from inositol pyrophosphates InsP5PP and InsP4(PP)2: a semi-empirical investigation

Christine E Hand  1 , John F Honek
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Phosphate transfer from inositol pyrophosphates InsP5PP and InsP4(PP)2: a semi-empirical investigation

Christine E Hand et al. Bioorg Med Chem Lett. .

Abstract

A novel phosphate transfer process involving the non-enzymatic transfer of a phosphate group from inositol pyrophosphates to serine residues in proteins has been recently reported. Semi-empirical calculations at the PM3/SM5.2 level were undertaken to explore the effect of inositol pyrophosphate structure and overall charge on the thermodynamics of this phosphate transfer.

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