doi: 10.1039/b612992g.
Epub 2006 Nov 14.
Spiroketals via oxidative rearrangement of enol ethers
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- PMID: 17164906
- DOI: 10.1039/b612992g
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Spiroketals via oxidative rearrangement of enol ethers
Org Biomol Chem.
.
Abstract
Oxidative rearrangement of cyclic enol ethers leads to alpha-alkoxyesters. In the presence of a neighboring spiroether, this approach provides a stereoselective access to spiroketals. A modified proposal for the biosynthesis of acutumine is presented.
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