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. 2007 Jan 7;5(1):58-60.
doi: 10.1039/b612992g. Epub 2006 Nov 14.

Spiroketals via oxidative rearrangement of enol ethers

David L Waller  1 , Corey R J Stephenson, Peter Wipf
Affiliations

Spiroketals via oxidative rearrangement of enol ethers

David L Waller et al. Org Biomol Chem. .

Abstract

Oxidative rearrangement of cyclic enol ethers leads to alpha-alkoxyesters. In the presence of a neighboring spiroether, this approach provides a stereoselective access to spiroketals. A modified proposal for the biosynthesis of acutumine is presented.

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