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. 2007 Jan 21;5(2):236-8.
doi: 10.1039/b617022f. Epub 2006 Nov 29.

Photo-Fries reaction in water made selective with a capsule

Lakshmi S Kaanumalle  1 , Corinne L D Gibb, Bruce C Gibb, V Ramamurthy
Affiliations

Photo-Fries reaction in water made selective with a capsule

Lakshmi S Kaanumalle et al. Org Biomol Chem. .

Abstract

The water soluble capsule formed by a deep cavity cavitand with eight carboxylic acid groups controls product distribution during photo-Fries rearrangement of naphthyl esters in water by restricting the mobility of primary singlet radical pair.

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