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. 2007 Feb 14:(6):616-8.
doi: 10.1039/b613019d. Epub 2006 Nov 7.

Highly enantioselective nitroaldol reaction catalyzed by new chiral copper complexes

Marco Bandini  1 , Fabio Piccinelli, Simona Tommasi, Achille Umani-Ronchi, Caterina Ventrici
Affiliations

Highly enantioselective nitroaldol reaction catalyzed by new chiral copper complexes

Marco Bandini et al. Chem Commun (Camb). .

Abstract

Remarkable generality in scope of DATs/Cu catalysts for enantioselective nitroaldol reaction is described; excellent levels of stereoinduction are recorded for a range of aldehydes (ee 81-99%, 17 examples) and the possibility to employ the present catalytic system as the key step for the preparation of highly functionalized tetrahydro-isoquinolines is demonstrated.

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