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. 2006 Oct 1:(37):3894-6.
doi: 10.1039/b607277a. Epub 2006 Aug 9.

Single-turnover intermolecular reaction between a Fe(III)-superoxide-Cu(I) cytochrome c oxidase model and exogeneous Tyr244 mimics

James P Collman  1 , Richard A Decréau, Christopher J Sunderland
Affiliations

Single-turnover intermolecular reaction between a Fe(III)-superoxide-Cu(I) cytochrome c oxidase model and exogeneous Tyr244 mimics

James P Collman et al. Chem Commun (Camb). .

Abstract

An Fe(III)-superoxide-Cu(I) cytochrome c oxidase model reacts intermolecularly with hindered phenols leading to phenoxyl radicals, as was observed in the enzyme and evidence for the formation of an Fe(IV)-oxo is presented.

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