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. 2007 Jan 7:(1):79-81.
doi: 10.1039/b612740a. Epub 2006 Nov 17.

Dihydroxylation of 2-vinylaziridine: efficient synthesis of D-ribo-phytosphingosine

Hyo Jae Yoon  1 , Yong-Woo Kim, Baeck Kyoung Lee, Won Koo Lee, Yongeun Kim, Hyun-Joon Ha
Affiliations

Dihydroxylation of 2-vinylaziridine: efficient synthesis of D-ribo-phytosphingosine

Hyo Jae Yoon et al. Chem Commun (Camb). .

Abstract

An efficient and highly stereoselective synthesis of D-ribo-(2S,3S,4R)-phytosphingosine was accomplished in 62% overall yield starting from commercially available (2S)-hydroxymethylaziridine via osmium-catalyzed asymmetric dihydroxylation as a key step.

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