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. 2007 Apr 2;46(7):2365-7.
doi: 10.1021/ic070268s. Epub 2007 Mar 6.

Addition of S-H bonds across electron-deficient olefins catalyzed by well-defined copper(I) thiolate complexes

Samuel A Delp  1 , Colleen Munro-Leighton, Laurel A Goj, Magaly A Ramírez, T Brent Gunnoe, Jeffrey L Petersen, Paul D Boyle
Affiliations

Addition of S-H bonds across electron-deficient olefins catalyzed by well-defined copper(I) thiolate complexes

Samuel A Delp et al. Inorg Chem. .

Abstract

A series of monomeric (NHC)Cu(SR) (R = Ph or CH2Ph; NHC = N-heterocyclic carbene) complexes have been synthesized and fully characterized including single-crystal X-ray diffraction studies. These complexes catalyze the addition of S-H bonds across electron-deficient olefins to regioselectively produce "anti-Markovnikov" products.

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