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. 2007 Apr 26;9(9):1659-61.
doi: 10.1021/ol070325l. Epub 2007 Mar 28.

Asymmetric hydrogenation of enol phosphinates by iridium catalysts having N,P ligands

Pradeep Cheruku  1 , Suresh Gohil, Pher G Andersson
Affiliations

Asymmetric hydrogenation of enol phosphinates by iridium catalysts having N,P ligands

Pradeep Cheruku et al. Org Lett. .

Abstract

[reaction: see text] Enol phosphinates, which are structural analogues of enol acetates, have for the first time been employed as substrates for Ir-catalyzed asymmetric hydrogenation. A number of enol phosphinates have been synthesized and reduced successfully with up to and above 99% ee.

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