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. 2007 Feb 21:(7):698-700.
doi: 10.1039/b615335f. Epub 2006 Dec 19.

Gold(I)-catalysed arylation of 1,6-enynes: different site reactivity of cyclopropyl gold carbenes

Catelijne H M Amijs  1 , Catalina Ferrer, Antonio M Echavarren
Affiliations

Gold(I)-catalysed arylation of 1,6-enynes: different site reactivity of cyclopropyl gold carbenes

Catelijne H M Amijs et al. Chem Commun (Camb). .

Abstract

Gold(I)-catalysed addition of electron-rich arenes and heteroarenes to 1,6-enynes gives two different types of products by reaction of the intermediate cyclopropyl gold carbenes at the cyclopropane or at the carbene.

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