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. 2007 Feb 21:(7):710-2.
doi: 10.1039/b616969d. Epub 2007 Jan 18.

Enantioselective palladium-catalysed conjugate addition of arylsiloxanes

Francesca Gini  1 , Bart Hessen, Ben L Feringa, Adriaan J Minnaard
Affiliations

Enantioselective palladium-catalysed conjugate addition of arylsiloxanes

Francesca Gini et al. Chem Commun (Camb). .

Abstract

The complex formed from Pd(CH(3)CN)(4)(BF(4))(2) and (R,R)-MeDUPHOS is a highly enantioselective catalyst for the asymmetric conjugate addition of aryltriethylsiloxanes to a variety of unsaturated ketones, lactones and lactams.

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