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. 2007 May 8;23(10):5283-5.
doi: 10.1021/la070019g. Epub 2007 Apr 3.

Supramolecular polymers based on the quadruplex formation of ditopic guanosine macromonomers in nonaqueous media

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Supramolecular polymers based on the quadruplex formation of ditopic guanosine macromonomers in nonaqueous media

Gabor Pintér et al. Langmuir. .

Abstract

The formation of supramolecular polymeric aggregates with a molecular mass of 100 kDa in a nonaqueous solution from a telechelic dimer of isopropylidene guanosine in the presence of K(+) ions is reported. The possible structure of macromonomers resulting from the development of G4 quartets was deduced from DOSY NMR, circular dichroism spectra, and dynamic light scattering measurements.

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