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. 2007 May 10;9(10):1907-10.
doi: 10.1021/ol070456m. Epub 2007 Apr 14.

Synthesis of perfluoroalkylated benzenes and pyridines through cationic Rh(I)/modified BINAP-catalyzed chemo- and regioselective [2 + 2 + 2] cycloaddition

Ken Tanaka  1 , Hiromi Hara, Goushi Nishida, Masao Hirano
Affiliations

Synthesis of perfluoroalkylated benzenes and pyridines through cationic Rh(I)/modified BINAP-catalyzed chemo- and regioselective [2 + 2 + 2] cycloaddition

Ken Tanaka et al. Org Lett. .

Abstract

A convenient synthesis of perfluoroalkylated benzenes and pyridines has been achieved by a cationic Rh(I)/modified BINAP-complex-catalyzed chemo- and regioselective [2 + 2 + 2] cycloaddition of alkynes with a perfluoroalkylacetylene and a perfluoroalkylnitrile.

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