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. 2007 Jun 7;9(12):2413-6.
doi: 10.1021/ol0708166. Epub 2007 May 11.

Asymmetric synthesis of syn-alpha-substituted beta-amino ketones by using sulfinimines and prochiral Weinreb amide enolates

Franklin A Davis  1 , Minsoo Song
Affiliations

Asymmetric synthesis of syn-alpha-substituted beta-amino ketones by using sulfinimines and prochiral Weinreb amide enolates

Franklin A Davis et al. Org Lett. .

Abstract

Syn-alpha-substituted beta-amino Weinreb amides are new chiral building blocks for asymmetric synthesis of syn-alpha-substituted beta-amino acids, aldehydes, and ketones and are prepared by addition of prochiral lithium enolates of Weinreb amides to sulfinimines (N-sulfinyl imines).

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