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. 2007 Jul 9;46(14):5448-9.
doi: 10.1021/ic700843s. Epub 2007 Jun 13.

A novel metal-binding mode of thymine nucleobases: N3 and O4 chelation

José Ruiz  1 , María Dolores Villa, Venancio Rodríguez, Natalia Cutillas, Consuelo Vicente, Gregorio López, Delia Bautista
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A novel metal-binding mode of thymine nucleobases: N3 and O4 chelation

José Ruiz et al. Inorg Chem. .

Abstract

The syntheses and crystal structures of the first examples of an anionic 1-methylthymine [deprotonated at the endocyclic NH group N(3)] acting as a chelating ligand for the cis-Pd(C6F3H2)2 and cis-Pd(C6F5)2 moieties through N(3) and O(4) are reported.

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