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. 2007 Jul 19:(27):2805-7.
doi: 10.1039/b703887a. Epub 2007 Jun 11.

Tricarbonylmanganese(I)-lysozyme complex: a structurally characterized organometallic protein

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Tricarbonylmanganese(I)-lysozyme complex: a structurally characterized organometallic protein

Mathieu Razavet et al. Chem Commun (Camb). .

Abstract

The reaction of the new and structurally characterized covalent {Mn(CO)(3)(H(2)O)(2)}(+)-lysozyme adduct with NiS(4) and NiN(2)S(2) complexes generates binuclear Ni-Mn complexes; relevance to the reactivity of the protein-bound {Fe(CO)(CN)(2)} intermediate during maturation of [NiFe] hydrogenases is discussed.

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