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. 2007 Aug 16;9(17):3393-5.
doi: 10.1021/ol0713842. Epub 2007 Jul 19.

Iridium-catalyzed asymmetric allylic substitution with aryl zinc reagents

Alexandre Alexakis  1 , Samir El Hajjaji, Damien Polet, Xavier Rathgeb
Affiliations

Iridium-catalyzed asymmetric allylic substitution with aryl zinc reagents

Alexandre Alexakis et al. Org Lett. .

Abstract

Thanks to iridium catalysis, arylzinc reagents undergo regioselective allylic substitution with very high enantioselectivity, when associated with phosphoramidite ligands.

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