Open-cage fullerene derivatives having 11-, 12-, and 13-membered-ring orifices: chemical transformations of the organic addends on the rim of the orifice
- PMID: 17655360
- DOI: 10.1021/jo070796l
Open-cage fullerene derivatives having 11-, 12-, and 13-membered-ring orifices: chemical transformations of the organic addends on the rim of the orifice
Abstract
A novel open-cage [60]fullerene derivative, having two sulfur atoms on the rim of its 13-membered-ring orifice, has been isolated and characterized. Extensive studies on the N-MEM group reactivity of this as well as other previously reported open-cage [60]fullerene derivatives led to several new open-cage [60]fullerene adducts.
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