Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2007 Nov;101(11-12):1758-9.
doi: 10.1016/j.jinorgbio.2007.07.004. Epub 2007 Jul 16.

[FeIII(SR)4]1- complexes can be synthesized by the direct reaction of thiolates with FeCl3

Sechin Chang  1 , Stephen A Koch
Affiliations

[FeIII(SR)4]1- complexes can be synthesized by the direct reaction of thiolates with FeCl3

Sechin Chang et al. J Inorg Biochem. 2007 Nov.

Abstract

It is shown that the previously characterized [Fe(III)(SR)(4)](1-) (R=Et, i-Pr, Ph) complexes can be synthesized by the direct reaction of 4equiv. of LiSR with FeCl(3) in DMF solution. [Fe(III)(SR)(4)](1-) complexes are synthetic analogs for the [Fe(III)(S-Cys)(4)] center in rubredoxin proteins.

PubMed Disclaimer

Similar articles

See all similar articles

References

    1. Meyer J, Moulis JM. Handbook of Metalloproteins. 2001;1:505–517.
    1. Sieker LC, Stenkamp RE, LeGall J. Methods Enzymol. 1994;243:203–216. - PubMed
    1. Romao MJ, Archer M. In: Iron Metabolism. Ferreira GC, Moura JJG, Franco R, editors. Wiley-VCH Verlag; Weinheim: 1999. pp. 341–358.
    1. Lane RW, Ibers JA, Frankel RB, Holm RH. Proc Natl Acad Sci U S A. 1975;72:2868–2872. - PMC - PubMed
    1. Lane RW, Ibers JA, Frankel RB, Papaefthymiou GC, Holm RH. J Am Chem Soc. 1977;99:84–98. - PubMed

Publication types