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. 1990 Nov 23;250(4984):1118-21.
doi: 10.1126/science.250.4984.1118.

Fabrication and use of nanometer-sized electrodes in electrochemistry

R M Penner, M J Heben, T L Longin, N S Lewis

Fabrication and use of nanometer-sized electrodes in electrochemistry

R M Penner et al. Science. .

Abstract

Electrodes with electrochemical dimensions as small as 10 angstroms have been fabricated and used for electrochemical studies. These nanometer-scale electrodes have enabled the measurement of electron-transfer rate constants, k(het), that are two orders of magnitude faster than k(het) values accessible with any other electrochemical method.

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