doi: 10.1039/b712758h.
Epub 2007 Oct 1.
On the structure of a proposed mixed-valent analogue of the diiron subsite of [FeFe]-hydrogenase
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- PMID: 17957282
- DOI: 10.1039/b712758h
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On the structure of a proposed mixed-valent analogue of the diiron subsite of [FeFe]-hydrogenase
Chem Commun (Camb).
.
Abstract
We show that a dinuclear assembly apparently providing the first example of a synthetic molecule exhibiting key features of the diiron subsite of [FeFe] hydrogenase, viz. CO-bridging of a coordinatively unsaturated, dithiolate-bridged mixed-valence diiron centre, is in fact a diamagnetic tetranuclear complex.
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