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. 2007 Nov;63(Pt 11):m494-5.
doi: 10.1107/S010827010704694X. Epub 2007 Oct 13.

Bis[N-(4-nitrophenyl)thiobenzamidato]mercury(II)

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Bis[N-(4-nitrophenyl)thiobenzamidato]mercury(II)

Mohammad Hossein Habibi et al. Acta Crystallogr C. 2007 Nov.

Abstract

The molecule of the title compound, [Hg(C(13)H(9)N(2)O(2)S)(2)], has approximate twofold rotation symmetry, with the Hg atom in an essentially linear two-coordinate HgS(2) environment supported by secondary pi interactions with the nitrophenyl rings of both ligands. The ligands are in the imine-thiolate rather than the amine-thione tautomeric form.

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