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. 2007 Dec 20;9(26):5397-400.
doi: 10.1021/ol702291r. Epub 2007 Nov 30.

Simple palladium(II) precatalyst for Suzuki-Miyaura couplings: efficient reactions of benzylic, aryl, heteroaryl, and vinyl coupling partners

Michael J Burns  1 , Ian J S Fairlamb, Anant R Kapdi, Petr Sehnal, Richard J K Taylor
Affiliations

Simple palladium(II) precatalyst for Suzuki-Miyaura couplings: efficient reactions of benzylic, aryl, heteroaryl, and vinyl coupling partners

Michael J Burns et al. Org Lett. .

Abstract

trans-PdBr(N-Succ)(PPh3)2 (1) is a universally effective precatalyst for Suzuki-Miyaura cross-couplings of benzylic halides with aryl- or heteroarylboronic acids. Substituted aryl halides and halogenated cyclic enones can be cross-coupled with aryl- or vinylboronic acids in excellent yields. Catalyst recycling is also demonstrated.

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