doi: 10.1039/b714526h.
Epub 2007 Oct 17.
Decarboxylative reduction of free aliphatic carboxylic acids by photogenerated cation radical
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- PMID: 18060156
- DOI: 10.1039/b714526h
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Decarboxylative reduction of free aliphatic carboxylic acids by photogenerated cation radical
Chem Commun (Camb).
.
Abstract
The decarboxylation of free carboxylic acids was effected by a photogenerated cation radical of phenanthrene to yield the reduction product in the presence of a thiol, which provides an alternative method to the Barton decarboxylation procedure for aliphatic acids such as N-Boc amino acids.
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