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. 2008 Jan 18;73(2):749-51.
doi: 10.1021/jo702167u. Epub 2007 Dec 21.

Chiral N-heterocyclic carbene--Pd(0)-catalyzed asymmetric diamination of conjugated dienes and triene

Liang Xu  1 , Yian Shi
Affiliations

Chiral N-heterocyclic carbene--Pd(0)-catalyzed asymmetric diamination of conjugated dienes and triene

Liang Xu et al. J Org Chem. .

Abstract

Studies show that a variety of conjugated dienes and triene can be enantioselectively diaminated using di-tert-butyldiaziridinone as nitrogen source and chiral N-heterocyclic carbene-Pd(0) complex as catalyst in good enantioselectivity (62-91% ee) with high regio- and diastereoselectivity.

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