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. 2008 Feb 15;73(4):1624-7.
doi: 10.1021/jo7022558. Epub 2008 Jan 17.

Nickel-catalyzed amination of aryl tosylates

Cai-Yan Gao  1 , Lian-Ming Yang
Affiliations

Nickel-catalyzed amination of aryl tosylates

Cai-Yan Gao et al. J Org Chem. .

Abstract

The cross-coupling of aryl tosylates with amines and anilines was accomplished by using a Ni-based catalyst system from the combination of Ni(II)-(sigma-aryl) complexes/N-heterocyclic carbenes (NHCs). The feature, scope, and limitation of this reaction are disclosed.

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