Simple rhodium-chlorophosphine pre-catalysts for the ortho-arylation of phenols
- PMID: 18283359
- DOI: 10.1039/b718128k
Simple rhodium-chlorophosphine pre-catalysts for the ortho-arylation of phenols
Abstract
Simple chlorodiisopropylphosphine adducts of rhodium, either pre-formed or formed in situ, prove to be highly effective catalysts for the ortho-arylation of phenols.
Similar articles
-
An octahedral rhodium cluster with six phosphine and 12 hydride ligands and 10 too few electrons.Angew Chem Int Ed Engl. 2004 Nov 19;43(45):6028-30. doi: 10.1002/anie.200460924. Angew Chem Int Ed Engl. 2004. PMID: 15538758 No abstract available.
-
Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines.Chem Commun (Camb). 2004 Nov 7;(21):2408-9. doi: 10.1039/b408856e. Epub 2004 Sep 23. Chem Commun (Camb). 2004. PMID: 15514789
-
Toward autonomously operating molecular machines driven by transition-metal catalyst.Mol Biosyst. 2008 Jun;4(6):512-4. doi: 10.1039/b801621f. Epub 2008 Apr 18. Mol Biosyst. 2008. PMID: 18493646
-
Synergistic effect of binary component ligands in chiral catalyst library engineering for enantioselective reactions.Chem Commun (Camb). 2008 Feb 28;(8):909-21. doi: 10.1039/b710668h. Epub 2008 Jan 21. Chem Commun (Camb). 2008. PMID: 18283341 Review.
-
Modular phospholane ligands in asymmetric catalysis.Acc Chem Res. 2000 Jun;33(6):363-72. doi: 10.1021/ar990085c. Acc Chem Res. 2000. PMID: 10891054 Review.
Cited by
-
Rhodium(i)-catalyzed cascade C(sp2)-H bond alkylation - amidation of anilines: phosphorus as traceless directing group.Chem Sci. 2023 Aug 1;14(34):9055-9062. doi: 10.1039/d3sc02992a. eCollection 2023 Aug 30. Chem Sci. 2023. PMID: 37655033 Free PMC article.
-
Double-fold C-H oxygenation of arenes using PyrDipSi: a general and efficient traceless/modifiable silicon-tethered directing group.J Am Chem Soc. 2012 Mar 28;134(12):5528-31. doi: 10.1021/ja3010545. Epub 2012 Mar 19. J Am Chem Soc. 2012. PMID: 22414133 Free PMC article.
-
Rhodium(i) complexes derived from tris(isopropyl)-azaphosphatrane-controlling the metal-ligand interplay.RSC Adv. 2021 Nov 22;11(59):37383-37391. doi: 10.1039/d1ra07126b. eCollection 2021 Nov 17. RSC Adv. 2021. PMID: 35496436 Free PMC article.
-
Csp2-H functionalization of phenols: an effective access route to valuable materials via Csp2-C bond formation.Chem Sci. 2024 Feb 21;15(11):3831-3871. doi: 10.1039/d4sc00687a. eCollection 2024 Mar 13. Chem Sci. 2024. PMID: 38487228 Free PMC article. Review.
-
The efficient desymmetrization of glycerol using scaffolding catalysis.Chem Commun (Camb). 2013 May 14;49(39):4370-2. doi: 10.1039/c2cc33633b. Chem Commun (Camb). 2013. PMID: 22790118 Free PMC article.
Publication types
MeSH terms
Substances
LinkOut - more resources
Full Text Sources
Other Literature Sources