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. 2008 Mar 20;10(6):1175-8.
doi: 10.1021/ol8000766. Epub 2008 Feb 23.

Air- and water-stable catalysts for hydroamination/cyclization. Synthesis and application of CCC-NHC pincer complexes of Rh and Ir

Eike B Bauer  1 , G T Senthil Andavan, T Keith Hollis, Ramel J Rubio, Joon Cho, Glenn R Kuchenbeiser, Theodore R Helgert, Christopher S Letko, Fook S Tham
Affiliations

Air- and water-stable catalysts for hydroamination/cyclization. Synthesis and application of CCC-NHC pincer complexes of Rh and Ir

Eike B Bauer et al. Org Lett. .

Abstract

The scope of CCC-NHC pincer complex synthetic methodology by metalation/transmetalation has been extended to Ir. Structural characterization revealed that it is isomorphous with the Rh complex. Both Rh and Ir complexes are efficient catalysts for the hydroamination/cyclization of secondary amines in the presence of air and/or water.

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