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. 2008 Jul 15;24(14):7245-50.
doi: 10.1021/la800227x. Epub 2008 Mar 21.

High uptakes of CO2 and CH4 in mesoporous metal-organic frameworks MIL-100 and MIL-101

Philip L Llewellyn  1 , Sandrine Bourrelly, Christian Serre, Alexandre Vimont, Marco Daturi, Lomig Hamon, Guy De Weireld, Jong-San Chang, Do-Young Hong, Young Kyu Hwang, Sung Hwa Jhung, Gérard Férey
Affiliations

High uptakes of CO2 and CH4 in mesoporous metal-organic frameworks MIL-100 and MIL-101

Philip L Llewellyn et al. Langmuir. .

Abstract

Mesoporous MOFs MIL-100 and MIL-101 adsorb huge amounts of CO2 and CH4. Characterization was performed using both manometry and gravimetry in different laboratories for isotherms coupled with microcalorimetry and FTIR to specify the gas-solid interactions. In particular, the uptake of carbon dioxide in MIL-101 has been shown to occur with a record capacity of 40 mmol g(-1) or 390 cm3STP cm(-3) at 5 MPa and 303 K.

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