doi: 10.1039/b718598g.
Epub 2008 Mar 6.
Lewis acid-catalyzed hydrogenation: B(C6F5)3-mediated reduction of imines and nitriles with H2
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- PMID: 18368170
- DOI: 10.1039/b718598g
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Lewis acid-catalyzed hydrogenation: B(C6F5)3-mediated reduction of imines and nitriles with H2
Chem Commun (Camb).
.
Abstract
The Lewis acid B(C(6)F(5))(3) has been found to be an efficient catalyst for the direct hydrogenation of imines and the reductive ring-opening of aziridines with H(2) under mild conditions; addition of a bulky phosphine allows for the reduction of protected nitriles.
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