Influence of carboxylic anhydrides on selected mechanical properties of heat-cured resin composites

Abstract

Resin composites are still in need of improved abrasion resistance for them to be ideal restorative materials for use in large occlusal cavities. The present study proposes a concept for additional cross-linking of dental monomers, by which mechanical properties and possibly the resistance to abrasion of the resin composites are increased. Cyclic acid anhydrides were added as cross-linking agents to different monomer mixtures, which were then loaded with filler. The monomer mixtures were varied with respect to type and ratio of monomer and anhydride. For measurement of diametral tensile strength, flexural strength, modulus of elasticity, and modulus of resilience, specimens were initially cured by light and then post-cured for one h at 150 degrees C. Resin composites based on UEDMA and HEMA were found to be superior to BISGMA- and TEGDMA-based composites. Increases in mechanical properties were highest when unsaturated anhydrides were used. An optimal effect of anhydride addition was found in resin composites also containing methacrylamide. Such materials resulted in a 20% increase in the mechanical properties investigated.