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. 2008 May 1;10(9):1815-8.
doi: 10.1021/ol800409d. Epub 2008 Apr 3.

Ir-catalyzed regio- and enantioselective Friedel-Crafts-type allylic alkylation of indoles

Wen-Bo Liu  1 , Hu He, Li-Xin Dai, Shu-Li You
Affiliations

Ir-catalyzed regio- and enantioselective Friedel-Crafts-type allylic alkylation of indoles

Wen-Bo Liu et al. Org Lett. .

Abstract

Highly regio- and enantioselective Ir-catalyzed Friedel-Crafts type allylic alkylation of indoles have been realized using [Ir(COD)Cl]2/phosphoramidite ligand 1a, affording the branched products with up to >97/3 branched-linear ratio and 92% ee.

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