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. 2008 Jun 6;73(11):3996-4003.
doi: 10.1021/jo800246g. Epub 2008 May 1.

Enantioselective Baeyer-Villiger oxidation catalyzed by palladium(II) complexes with chiral P,N-ligands

Andrei V Malkov  1 , Frédéric Friscourt, Mark Bell, Martin E Swarbrick, Pavel Kocovský
Affiliations

Enantioselective Baeyer-Villiger oxidation catalyzed by palladium(II) complexes with chiral P,N-ligands

Andrei V Malkov et al. J Org Chem. .

Abstract

Asymmetric Baeyer-Villiger reaction of symmetrical cyclobutanones 1a-j with urea-hydrogen peroxide (UHP) can be catalyzed by a complex of Pd(II) and the new terpene-derived P, N-ligand 7. The resulting lactones 2a-j were obtained in high yields and with good enantioselectivity (< or =81% ee).

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