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. 2008 Jun 18;130(24):7556-7.
doi: 10.1021/ja802704j. Epub 2008 May 21.

Asymmetric imino aza-enamine reaction catalyzed by axially chiral dicarboxylic acid: use of arylaldehyde N,N-dialkylhydrazones as acyl anion equivalent

Takuya Hashimoto  1 , Maya Hirose, Keiji Maruoka
Affiliations

Asymmetric imino aza-enamine reaction catalyzed by axially chiral dicarboxylic acid: use of arylaldehyde N,N-dialkylhydrazones as acyl anion equivalent

Takuya Hashimoto et al. J Am Chem Soc. .

Abstract

Synthetic utility of arylaldehyde N,N-dialkylhydrazones as a practical acyl anion equivalent could be exploited for the first time in the asymmetric imino aza-enamine reaction catalyzed by axially chiral carboxylic acid.

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