Toward autonomously operating molecular machines driven by transition-metal catalyst
- PMID: 18493646
- DOI: 10.1039/b801621f
Toward autonomously operating molecular machines driven by transition-metal catalyst
Abstract
A Vaska-type complex carrying a ferrocene-appended diphosphine ligand was developed as a prototype of autonomous molecular machines that is able to undergo continuous scissoring motion in the presence of diphenylphosphoryl azide and aldehyde.
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